October 2009

Salt: No Easy Answers

There’s no substitute yet for road deicing salt, but local efforts are providing guidance for mitigating its ecological effects.

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Photo: iStockphoto.com/hbak

By Don Talend

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The issue of groundwater and surface water contamination resulting from road deicing salt use is one of contaminant mitigation, not best management practices (BMPs). Nothing can be done to remove salt and its compounds once they get into water supplies, so the management focus is on reducing or eliminating salt in point and nonpoint sources before stormwater becomes a carrier of pollution to groundwater and surface waters. For years, the deleterious effects of road salt on infrastructure—concrete reinforcing steel and pavements, most notably—has been well known, but the adverse effects of salt on the natural environment have come to the fore more recently.

The most common type of road salt is sodium chloride. High sodium concentrations in drinking water—above 20 milligrams per liter (mg/l)—can contribute to hypertension. Chloride is considered harmful, because it damages wildlife food resources and shelter and can change the composition of the plant community in a wetland and allow invasive plant species to populate it. An estimated 10% of aquatic species exceed their critical tolerance values for chloride with prolonged exposure to concentrations above 220 mg/l, but many macroinvertebrates exhibit lower tolerances.

Besides sodium and chloride, road salts may have smaller amounts of calcium, potassium, and magnesium chlorides, and sodium ferrocyanide is added to chloride salts to prevent clumping during storage and application. In water, sodium ferrocyanide can be photolyzed to release approximately 25% cyanide ions. In 2003, the USEPA listed ferrocyanide as a toxic pollutant and hazardous substance under Section 307(a) of the Clean Water Act. EPA and validated states have also set chronic and acute limits on chloride.

It is estimated that annual salt deicer usage totals 15 million tons in the United States and about 4 million to 5 million tons in Canada. One might wonder why road salt is still used, given its ecological harm. That’s until one considers the case for road salt as a public safety tool and economic catalyst in northern climates. Salt dissolves in water from snow and ice to form brine, which lowers the freezing point of water, and thus breaks the bond between the pavement and snow or ice.

Chloride ions are relatively stable, meaning that they can move through the environment in solution without being lost or broken down through natural processes. As a result, almost all chloride ions that enter the environment reach surface water. “It’s essentially conservative—that’s the term people use,” notes Roger Bannerman, environmental specialist for the Wisconsin Department of Natural Resources (DNR). “Sometimes it can build up to the point where the lake will cease having its normal cycles. Lakes tend to turn over and the water becomes homogenous and the temperature becomes even, but the chloride will create a density gradient where it won’t turn over anymore. And of course, if the chloride concentration gets high enough, things living in it can’t tolerate that high level.”

Adds Phil Trowbridge, P.E., a coastal scientist with the New Hampshire Department of Environmental Services (DES): “We don’t have stormwater BMPs that can remove chloride. The only way to reduce the salt impact is to reduce the salt load.”

Photo: Roger Bannerman
Salt dissolves in water from snow and ice to form brine, which lowers the freezing point of water, and thus breaks the bond between the pavement and snow or ice.

Organic substitutes for salt are not a panacea, Bannerman argues. “There are other calcium- and magnesium-based products coming out, but they still have chloride in them and they’re more expensive, unfortunately. I think one role EPA could play is to work on alternatives and fund research. Things like beet juice and other things are being tried. One thing we’re worried about is that any organic-based deicer might have high phosphorus content—that’s the last thing we can have.”

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Since no “silver bullet” for solving the road salt problem currently exists, several long-term mitigation efforts have been undertaken in recent years. These efforts represent the latest approaches and philosophies being used to attack a very daunting problem.

Madison, WI
The Wisconsin capital has been in the forefront of the deicing salt issue for nearly 40 years, starting when the city’s Common Council directed the City Streets Division to reduce the amount of road salt used for winter maintenance in the Lake Wingra watershed starting in the winter of 1972–73, with the rest of the city following suit by 1977–78. Despite this early awareness, and notwithstanding the fact that chloride concentrations in Madison lakes are generally well below Wisconsin DNR and EPA toxicity standards for surface waters, the concentrations have nearly doubled in recent decades. In the winter of 2004–05, 48% more road salt was applied to Madison’s 750 street miles compared with 1972–1973, adjusting for the difference in street miles maintained. Next Page >

What Do You Think?

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kitmartin

November 5th, 2009 10:01 AM PT

Thank you for an excellent article on the issue of deicing road salt. Although I have long been concerned about this matter in relation to potential environmental impacts, in truth, I know very little about the matter. This article that I came across by chance has refreshed my memory and opened my eyes to some of the current thinking. I hope to pursue the matter at the local and state level (in Gloucester and Massachusetts, repectively). Our coastal location presents some particular problems for the environment but we also obtain our drinking water from watershed runoff into reservoirs. Your discussion of some of the solutions being applied in other areas will guide me in my quest for answers here. Thanks, Chris

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